Some features of the hydrosilylation of vinylsilanes

Journal Article · Thu Jan 09 23:00:00 EST 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7101754

Sheludyakov, V D; Bochkarev, V N; Slyosarenko, T F; Vlasenko, S D; Zhun', V I

This paper presents a study on the hydrosilylation of mono-, di-, tri-, and tetravinylsilanes by trimethyl-, trichloro-, and methylchlorosilanes in the presence of Speier's catalyst. Variation of the catalyst or solvent upon hydrosilylation of the vinylsilanes may alter the direction of the addition of the hydrosilane to the C=C bond with formation of a 1,1- or 1,2-disilyl-substituted ethane. A scheme was proposed for the hydrosilylation of vinylsilane in the presence of Speier's catalyst using silicon analogs of Zeise salt.

• OSTI ID: 7101754
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:7, PT. 2; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
CARBON 13
CARBON ISOTOPES
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
COMPLEXES
ENERGY
EVEN-ODD NUCLEI
HYDRIDES
HYDROGEN COMPOUNDS
ISOMERS
ISOTOPES
KINETICS
LIGHT NUCLEI
MASS SPECTRA
MONOMERS
NMR SPECTRA
NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
PLATINUM COMPLEXES
POLYMERIZATION
REACTION KINETICS
SILANES
SILICON COMPOUNDS
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
VINYL MONOMERS