Preparation of free phenylvinyl cations by nuclear-chemical method and study of their reactions wit h benzene in liquid phase

Journal Article · Mon Sep 01 04:00:00 EDT 1986 · Sov. Radiochem. (Engl. Transl.); (United States)

OSTI ID:7004187

Nefedov, V D; Kuzhelev, L P; Lebedev, V P; Sinotova, E N

This paper studies ion-molecular reactions of free nucleogenic 1- and 2-phenylvinyl cations with benzene in liquid phase at room temperature. The reaction products were identified by means of gas radiochromatography. It was found that the main products of the ion-molecular reactions of free phenylvinyl cations with benzene are 1,1- and trans-1,2-diphenylethylenes during electrophilic substitution, and also phenylacetylene as the result of monomolecular proton elimination from the cation. Schemes of formation of the observed products in the reaction mixture are suggested.

• OSTI ID: 7004187
• Journal Information: Sov. Radiochem. (Engl. Transl.); (United States), Journal Name: Sov. Radiochem. (Engl. Transl.); (United States) Vol. 28:1; ISSN SVRDA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ALKYL RADICALS
AROMATICS
ARYL RADICALS
BENZENE
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
DECOMPOSITION
DISSOCIATION
GAS CHROMATOGRAPHY
HYDROCARBONS
ISOMERIZATION
ISOTOPE APPLICATIONS
KINETICS
LABELLED COMPOUNDS
LABELLING
ORGANIC COMPOUNDS
PHENYL RADICALS
RADICALS
RADIOCHROMATOGRAPHY
REACTION KINETICS
SEPARATION PROCESSES
SOLVOLYSIS
STILBENE
SYNTHESIS
TOLAN
TRACER TECHNIQUES
TRITIUM COMPOUNDS
VINYL RADICALS
YIELDS