Radiochemical study of ionic-molecular reactions of free phenylvinyl cations with certain oxygen-containing compounds

Journal Article · Tue Sep 01 04:00:00 EDT 1987 · Sov. Radiochem. (Engl. Transl.); (United States)

OSTI ID:5277052

Nefedov, V D; Sinotova, E N; Kuzhelev, L P; Lebedev, V P

The ionic molecular reactions of free phenylvinyl cations with water, ethanol, and diethyl ether in various aggregated states were studied by a radiochemical method. The free cations were produced by a nuclear chemical method (as a result of the ..beta.. decay of tritium atoms in styrene C/sub 6/H/sub 5/CT = CHT). It was shown that the main products are products of electrophilic addition: acetophenone, phenylethanal, and isomeric ethoxystyrenes. The competing process - deprotonation of the cations - leads to the formation of phenylacetylene. A quantum chemical interpretation of the results obtained is given within the framework of the theory of perturbation of molecular orbitals.

• OSTI ID: 5277052
• Journal Information: Sov. Radiochem. (Engl. Transl.); (United States), Journal Name: Sov. Radiochem. (Engl. Transl.); (United States) Vol. 29:1; ISSN SVRDA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400101 -- Activation
Nuclear Reaction
Radiometric & Radiochemical Procedures
400600* -- Radiation Chemistry
400702 -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACETOPHENONE
ALCOHOLS
ALKYL RADICALS
ALKYLATED AROMATICS
AROMATICS
ARYL RADICALS
ATOMIC MODELS
BETA DECAY
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY
BETA-MINUS DECAY RADIOISOTOPES
CATIONS
CHARGED PARTICLES
CHEMICAL ANALYSIS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
CHROMATOGRAPHY
DECAY
DECOMPOSITION
DEHYDROGENATION
ETHANOL
ETHERS
ETHYL ETHER
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
IONS
ISOMERIZATION
ISOMERS
ISOTOPES
KETONES
KINETICS
LABELLED COMPOUNDS
LABELLING
LIGHT NUCLEI
MATHEMATICAL MODELS
MECHANICS
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXYGEN COMPOUNDS
PHENYL RADICALS
QUANTITATIVE CHEMICAL ANALYSIS
QUANTUM MECHANICS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOCHEMICAL ANALYSIS
RADIOISOTOPES
RADIOLYSIS
REACTION KINETICS
SEPARATION PROCESSES
STYRENE
TOLAN
TRITIUM
TRITIUM COMPOUNDS
VINYL RADICALS
WATER
YEARS LIVING RADIOISOTOPES
YIELDS