Radiochemical study of reaction of free butyl cations with benzene in gas and condensed media

Journal Article · · Sov. Radiochem. (Engl. Transl.); (United States)

OSTI ID:6550085

Nefedov, V D; Sinotova, E N; Arkhipov, Yu M; Gomzina, N A

Ion-molecular reactions between free butyl cations obtained by nucleochemical technique and benzene in the gas, liquid, and solid phases have been studied. It has been proved that the main products of ion-molecular reaction of free butyl cations and benzene are isomeric n-, sec-, and tert-butyl benzenes in the gas phase and only n- and sec-butyl benzenes in the condensed media. An explanation has been offered for the probable processes giving the observed products.

• OSTI ID: 6550085
• Journal Information: Sov. Radiochem. (Engl. Transl.); (United States), Journal Name: Sov. Radiochem. (Engl. Transl.); (United States) Vol. 25:4; ISSN SVRDA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
AROMATICS
BENZENE
BUTANE
CATIONS
CHARGED PARTICLES
CHEMICAL ANALYSIS
CHEMICAL REACTIONS
FLUIDS
GASES
HYDROCARBONS
IONS
LIQUIDS
ORGANIC COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
RADIOCHEMICAL ANALYSIS
SOLIDS