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CIDNP in pulse radiolysis of aqueous dimethyl sulfoxide

Journal Article · · J. Phys. Chem.; (United States)
DOI:https://doi.org/10.1021/j100501a016· OSTI ID:6976832
Variable field CIDNP in pulse radiolysis of aqueous dimethyl sulfoxide is described. The products of radiolytically produced radicals are identified, and the radical pair model of CIDNP is applied in analysis of the observed polarization. Various mechanisms of radical formation and reaction are considered. 4 figures; 2 tables.
Research Organization:
Argonne National Lab., Il
OSTI ID:
6976832
Journal Information:
J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 82:12; ISSN JPCHA
Country of Publication:
United States
Language:
English

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Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ALCOHOLS
ALKANES
AQUEOUS SOLUTIONS
CHALCOGENIDES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
CRYOGENIC FLUIDS
DECOMPOSITION
DISPERSIONS
DMSO
ELEMENTS
ETHANE
FLUIDS
HELIUM
HYDROCARBONS
HYDROXY COMPOUNDS
IRRADIATION
KINETICS
MAGNETIC FIELDS
MAGNETIC RESONANCE
METHANE
METHANOL
MIXTURES
NITROGEN COMPOUNDS
NITROGEN OXIDES
NITROUS OXIDE
NONMETALS
NUCLEAR MAGNETIC RESONANCE
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PH VALUE
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOLYSIS
RARE GASES
REACTION KINETICS
RESONANCE
SOLUTIONS
SULFOXIDES
YIELDS