CIDNP/FTNMR as a mechanistic probe in the pulse radiolysis of aqueous acetone and acetaldehyde

Journal Article · Thu Aug 23 04:00:00 EDT 1979 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100480a002· OSTI ID:5711376

Nelson, D J

The utility of CIDNP/FTNMR in the study of reaction mechanism in pulse radiolysis of aqueous acetone and acetaldehyde is discussed. Using this technique, one can identify the principle radiolytic products. The high field polarization observed in these products is correlated with that expected from reactions of the radical intermediates most likely present in the solution, enabling identification of important reaction pathways. 6 figures, 5 tables.

• Research Organization: Argonne National Lab., IL
• OSTI ID: 5711376
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 83:17; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400302 -- Organic Chemistry-- Isotope Effects-- (-1987)
400600* -- Radiation Chemistry
ABSORPTION SPECTRA
ACETALDEHYDE
ACETONE
ALCOHOLS
ALDEHYDES
AQUEOUS SOLUTIONS
CHALCOGENIDES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
DATA
DATA FORMS
DECOMPOSITION
DEUTERIUM
DEUTERIUM COMPOUNDS
DISPERSIONS
ETHANOL
EXPERIMENTAL DATA
GLYCOLS
HYDRATES
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
INFORMATION
IRRADIATION
ISOLATED VALUES
ISOTOPE EFFECTS
ISOTOPES
KETONES
KINETICS
LIGHT NUCLEI
MAGNETIC RESONANCE
MIXTURES
NITROGEN COMPOUNDS
NITROGEN OXIDES
NITROUS OXIDE
NUCLEAR MAGNETIC RESONANCE
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PH VALUE
PROPANOLS
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
REACTION KINETICS
RESONANCE
SOLUTIONS
SPECTRA
STABLE ISOTOPES
YIELDS