CIDNP-detected nuclear resonance of transient radicals in pulse radiolysis

Journal Article · Wed Jul 02 04:00:00 EDT 1980 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00534a005· OSTI ID:6776047

Trifunac, A D; Evanochko, W T

CIDNP detection of nuclear resonance in transient radicals produced by pulse radiolysis is described. CIDNP intensities of the reaction products can be perturbed by the application of radio frequency corresponding to the nuclear resonance in the transient radicals. In addition to the measurement of hyperfine coupling constants of transient radicals, the pulsed nature of the variable-field CIDNP nuclear resonance technique in pulse radiolysis can be used to measure radical kinetics and to study CIDEP population dynamics in various magnetic fields.

• Research Organization: Argonne National Lab., IL
• DOE Contract Number: EY-76-C-02-0016
• OSTI ID: 6776047
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 102:14; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400302 -- Organic Chemistry-- Isotope Effects-- (-1987)
400600* -- Radiation Chemistry
ALCOHOLS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
DATA
DECOMPOSITION
DEUTERIUM
ELECTROMAGNETIC RADIATION
ELECTRONS
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
GLYCOLS
HALOGENATED ALIPHATIC HYDROCARBONS
HEAVY WATER
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
INFORMATION
IODINATED ALIPHATIC HYDROCARBONS
ISOTOPE EFFECTS
ISOTOPES
LEPTONS
LIGHT NUCLEI
MAGNETIC RESONANCE
METHANOL
METHYL IODIDE
NUCLEAR MAGNETIC RESONANCE
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
OXYGEN COMPOUNDS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADICALS
RADIOLYSIS
RADIOWAVE RADIATION
RESONANCE
STABLE ISOTOPES
WATER