Organometallic chemistry on a metallathiaborane cluster: Reactions of [8,8-(PPh{sub 3}){sub 2}-nido-8,7-RhSB{sub 9}H{sub 10}] with bidentate phosphine ligands
- Univ. of Missouri, St. Louis, MO (United States). Dept. of Chemistry
Reactions of the unsaturated cluster [8,8-(PPh{sub 3}){sub 2}-nido-8,7-RhSB{sub 9}H{sub 10}] (1) with the bidentate 1,n-bis(diphenylphosphino)alkanes (CH{sub 2}){sub n}(PPh{sub 2}){sub 2}, where n = 1--3 (abbreviated as dppm, dppe, and dppp, respectively), have been studied. The species have been characterized by NMR and mass spectrometry, and crystal structure determinations are described.
- Sponsoring Organization:
- National Science Foundation, Washington, DC (United States); USDOE, Washington, DC (United States); National Insts. of Health, Bethesda, MD (United States)
- DOE Contract Number:
- FG02-92CH10499
- OSTI ID:
- 696627
- Journal Information:
- Organometallics, Journal Name: Organometallics Journal Issue: 18 Vol. 18; ISSN ORGND7; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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