Organometallic chemistry on a metallathiaborane cluster: Reactions of [8,8-(PPh[sub 3])[sub 2]-nido-8,7-RhSB[sub 9]H[sub 10]] with bidentate phosphine ligands
- Univ. of Missouri, St. Louis, MO (United States). Dept. of Chemistry
Reactions of the unsaturated cluster [8,8-(PPh[sub 3])[sub 2]-nido-8,7-RhSB[sub 9]H[sub 10]] (1) with the bidentate 1,n-bis(diphenylphosphino)alkanes (CH[sub 2])[sub n](PPh[sub 2])[sub 2], where n = 1--3 (abbreviated as dppm, dppe, and dppp, respectively), have been studied. The species have been characterized by NMR and mass spectrometry, and crystal structure determinations are described.
- Sponsoring Organization:
- NSF; DOE; NIH; National Science Foundation, Washington, DC (United States); USDOE, Washington, DC (United States); National Insts. of Health, Bethesda, MD (United States)
- DOE Contract Number:
- FG02-92CH10499
- OSTI ID:
- 5937113
- Journal Information:
- Organometallics, Journal Name: Organometallics Vol. 18:18; ISSN ORGND7; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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