Isotope effect in the reaction of cumyl peroxide radical with benzaldehyde

Journal Article · Fri Aug 01 04:00:00 EDT 1986 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6952245

Simonov, M A; Opeida, I A; Romantsevich, A M

The rate constants for reaction of cumyl peroxide with benzaldehyde and benzaldehyde-D/sub 1/ have been measured; k /SUP H/ = 10 /SUP 7.61+or-0.18/ exp((-9.2 + or - 0.3)/RT) and k /SUP D/ = 10 /SUP 7.31+or-0.40/ exp ((-10.8 + or - 0.6)/RT) liter/mole.sec, respectively.

• Research Organization: Institute of Physiio, organic Chemistry, Ukrainian SSR Acad. of Sci., Donetsk
• OSTI ID: 6952245
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 27:1, PT. 2; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400202* -- Isotope Effects
Isotope Exchange
& Isotope Separation
ACTIVATION ENERGY
ALDEHYDES
BENZALDEHYDE
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DEUTERIUM COMPOUNDS
ENERGY
FLAMES
HYDROGEN COMPOUNDS
IONIZATION
ISOTOPE EFFECTS
KINETICS
ORGANIC COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PEROXIDES
REACTION KINETICS
SAMPLE PREPARATION