Spectroscopic studies of diatomic noble gas halides. III. Analysis of XeF 3500 A band system

Journal Article · Thu Jun 01 00:00:00 EDT 1978 · J. Chem. Phys.; (United States)

DOI:https://doi.org/10.1063/1.435582· OSTI ID:6938292

Tellinghuisen, J; Tellinghuisen, P C; Tisone, G C; Hoffman, J M; Hays, A K

B..-->..X spontaneous and stimulated emission spectra of XeF have been photographed at medium resolution (2.0 A/mm) and vibrationally analyzed. The assignments are made with the aid of trial-and-error Franck--Condon calculations and band profile simulations, which are described in detail. The strong laser emission near 3511 A is primarily due to densely overlapped rotational lines in the 1--4 vibronic band, and that near 3532 A probably includes numerous rotational transitions in the 0--2, 0--3, and 1--6 bands.

• Research Organization: Department of Chemistry, Vanderbilt University, Nashville, Tennessee 37235
• OSTI ID: 6938292
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 68:11; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

42 ENGINEERING
420300* -- Engineering-- Lasers-- (-1989)
EMISSION
EMISSION SPECTRA
ENERGY-LEVEL TRANSITIONS
FLUORIDES
FLUORINE COMPOUNDS
FRANCK-CONDON PRINCIPLE
GAS LASERS
HALIDES
HALOGEN COMPOUNDS
LASERS
RARE GAS COMPOUNDS
SPECTRA
STIMULATED EMISSION
ULTRAVIOLET SPECTRA
XENON COMPOUNDS
XENON FLUORIDES