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Deposition of copper indium diselenide films by low-cost techniques: Final subcontractor report, 15 November 1983 to 14 September 1985

Technical Report ·
DOI:https://doi.org/10.2172/6889492· OSTI ID:6889492
This is the final technical report of a research program on copper indium diselenide films. The objectives of this program were to prepare device-quality, thin-film, polycrystalline CuInSe/sub 2/ by low-cost techniques and to produce heterojunction solar cells 1 cm/sup 2/ in area with an AM 1 efficiency of 8% or higher. In this work, three approaches were used to deposit p-type CuInSe/sub 2/ films: close-spaced chemical vapor transport (CSCVT), thermal reduction of Cu and In compounds followed by selenization, and electroplating of Cu and In films followed by selenization. The important process parameters for: (1) depositing CuInSe/sub 2/ films by the CSCVT technique; (2) depositing Cu-In films by chemical reduction and electroplating; and (3) forming CuInSe/sub 2/ films by the selenization of Cu-In films were investigated. Many p-CuInSe/sub 2/ films were deposited on conducting and insulating substrates, and their properties characterized. Heterojunction solar cells were fabricated from p-CuInSe/sub 2/ films prepared by the three techniques, and their photovoltaic characteristics evaluated. The procedures and results are summarized.
Research Organization:
Poly Solar, Inc., Garland, TX (USA)
DOE Contract Number:
AC02-83CH10093
OSTI ID:
6889492
Report Number(s):
SERI/STR-211-3123; ON: DE87001151
Country of Publication:
United States
Language:
English