Photolysis of aryl chlorides with dienes and with aromatic amines
Journal Article
·
· J. Org. Chem.; (United States)
Simple dienes quench the fluorescence of 1-chloronaphthalene and 4-chlorobiphenyl with a concurrent singlet-state photochemical reaction, which does not involve dechlorination. Similar chemistry is brought about when the diene is initially excited. Chlorobiphenyls quench the fluorescence of N,N-dimethylaniline with concomitant photodechlorination of the aryl chloride. Attempts to extent this reaction to amines having longer wavelength absorption were unsuccessful.
- Research Organization:
- Univ. of Guelph, Canada
- OSTI ID:
- 6819481
- Journal Information:
- J. Org. Chem.; (United States), Journal Name: J. Org. Chem.; (United States) Vol. 47:10; ISSN JOCEA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
500200 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
AMINES
ANILINE
AROMATICS
BIPHENYL
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED AROMATIC HYDROCARBONS
CONDENSED AROMATICS
DATA
DECOMPOSITION
DIENES
ELECTRON TRANSFER
EXPERIMENTAL DATA
HALOGENATED AROMATIC HYDROCARBONS
HYDROCARBONS
INFORMATION
KINETICS
NAPHTHALENE
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
POLYENES
QUANTITY RATIO
REACTION KINETICS
REDUCTION
400500* -- Photochemistry
500200 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
AMINES
ANILINE
AROMATICS
BIPHENYL
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED AROMATIC HYDROCARBONS
CONDENSED AROMATICS
DATA
DECOMPOSITION
DIENES
ELECTRON TRANSFER
EXPERIMENTAL DATA
HALOGENATED AROMATIC HYDROCARBONS
HYDROCARBONS
INFORMATION
KINETICS
NAPHTHALENE
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
POLYENES
QUANTITY RATIO
REACTION KINETICS
REDUCTION