Dynamics of contact radical ion pairs C{sub 60}-aromatic amines. A study by picosecond laser photolysis

Journal Article · Thu Jun 01 00:00:00 EDT 1995 · Russian Chemical Bulletin

DOI:https://doi.org/10.1007/BF00707050· OSTI ID:161906

Nadtochenko, N A; Denisov, N N; Levin, P P ^[1]

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1. Inst. of Chemical Physics in Chernogolovka, Moscow (Russian Federation)

Charge transfer complexes between C{sub 60} and ternary aromatic amines (N,N,N{prime},N{prime}-tetramethyl-p-phenylenediamine, p-methoxy-N,N-dimethylaniline, p-methyl-N,N-dimethylaniline, N,N-diethylaniline, N,N-dimethylaniline, and triphenylamine) were studied in chlorobenzene solutions. The lifetimes of the excited state with charge transfer in these complexes were measured by the method of picosecond laser photolysis. The dependence of the rate constant of the back electron transfer on {delta}G in the back electron transfer reaction with relaxation of the charge-transfer state exhibits the {open_quotes}Marcus-inverted{close_quotes} region.

• Sponsoring Organization: USDOE
• OSTI ID: 161906
• Journal Information: Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 6 Vol. 44; ISSN 1066-5285; ISSN RCBUEY
• Country of Publication: United States
• Language: English

Related Subjects

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