Reduction of aliphatic and aromatic N-oxides to the corresponding amines with titanium(III) chloride
Journal Article
·
· Anal. Biochem.; (United States)
Amine N-oxides have been observed to be reduced by titanium(III) chloride. To study this reaction, 24 model amine N-oxides were reacted with titanium(III) chloride. The products of these reactions were shown by melting (boiling) points, derivatives, refractive indices, infrared, and NMR comparisons with authentic compounds to be the corresponding amines. The reductions were found to require 2 moles of titanium(III) per mole of amine N-oxide.
- Research Organization:
- Lamar Univ., Beaumont, TX
- OSTI ID:
- 6740266
- Journal Information:
- Anal. Biochem.; (United States), Journal Name: Anal. Biochem.; (United States) Vol. 138:1; ISSN ANBCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
ALKENES
ALKYNES
AMINES
AROMATICS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFRARED SPECTRA
MELTING POINTS
NITROGEN COMPOUNDS
NITROGEN OXIDES
NMR SPECTRA
OPTICAL PROPERTIES
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
REDUCTION
REFRACTIVITY
SPECTRA
SPECTROSCOPY
STOICHIOMETRY
THERMODYNAMIC PROPERTIES
TITANIUM CHLORIDES
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION TEMPERATURE
YIELDS
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
ALKENES
ALKYNES
AMINES
AROMATICS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFRARED SPECTRA
MELTING POINTS
NITROGEN COMPOUNDS
NITROGEN OXIDES
NMR SPECTRA
OPTICAL PROPERTIES
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
REDUCTION
REFRACTIVITY
SPECTRA
SPECTROSCOPY
STOICHIOMETRY
THERMODYNAMIC PROPERTIES
TITANIUM CHLORIDES
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION TEMPERATURE
YIELDS