Synthesis and characterization of novel yttrium-copper alkoxide clusters
Journal Article
·
· Inorganic Chemistry; (United States)
- Univ. of Zuerich (Switzerland)
On reaction of [Y(OCH[sub 2]CH[sub 2]OMe)[sub 3]][sub 10] (2) with [(thd)Cu(OCH[sub 2]CH[sub 2]OMe)][sub 4] (1a) and [(hfd)Cu(OCH[sub 2]CH[sub 2]OMe)][sub 4] (1b) (thd = 2,2,6,6-tetramethyl-3,5-heptanedione; hfd = 1,1,1,5,5,5-hexafluoroacetylacetone), the mixed-metal clusters (thd)[sub 4]Cu[sub 3]Y(OCH[sub 2]CH[sub 2]OMe)[sub 5] (3), [(hfd)[sub 2]CuY(OCH[sub 2]CH[sub 2]OMe)[sub 3]][sub 2] (4), and (hfd)[sub 2](thd)[sub 2]Cu[sub 2]Y(OCH[sub 2]CH[sub 2]OMe)[sub 3] (5) are formed. Their elemental analyses and IR and vis spectroscopic data are reported. 14 refs., 3 figs., 10 tabs.
- OSTI ID:
- 6725303
- Journal Information:
- Inorganic Chemistry; (United States), Journal Name: Inorganic Chemistry; (United States) Vol. 32:5; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ABSORPTION SPECTROSCOPY
ALKOXIDES
CHEMICAL PREPARATION
COHERENT SCATTERING
COPPER COMPOUNDS
CRYSTAL STRUCTURE
DIFFRACTION
MOLECULAR STRUCTURE
SCATTERING
SPECTROSCOPY
STOICHIOMETRY
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
X-RAY DIFFRACTION
YTTRIUM COMPOUNDS
400201* -- Chemical & Physicochemical Properties
ABSORPTION SPECTROSCOPY
ALKOXIDES
CHEMICAL PREPARATION
COHERENT SCATTERING
COPPER COMPOUNDS
CRYSTAL STRUCTURE
DIFFRACTION
MOLECULAR STRUCTURE
SCATTERING
SPECTROSCOPY
STOICHIOMETRY
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
X-RAY DIFFRACTION
YTTRIUM COMPOUNDS