Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Kinetic generation of cis-C[sub 5]H[sub 5](CO)[sub 2]ReH[sub 2] from the reaction of C[sub 5]H[sub 5](CO)[sub 2]Re([mu]-H)Pt(H)(PPh[sub 3])[sub 2] with diphenylacetylene

Journal Article · · Inorganic Chemistry; (United States)
DOI:https://doi.org/10.1021/ic00052a024· OSTI ID:6724601
; ; ; ;  [1]
  1. Univ. of Wisconsin, Madison (United States)
+ Show Author Affiliations
Protonation of K[C[sub 5]H[sub 5](CO)[sub 2]ReH] with CF[sub 3]CO[sub 2]H at [minus]78[degrees]C produced a 65:35 mixture of cis-C[sub 5]H[sub 5](CO)[sub 2]ReH[sub 2] (cis-1) and trans-C[sub 5]H[sub 5](CO)[sub 2]ReH[sub 2] (trans-1). At 24[degrees]C, this mixture equilibrated to a 2:98 cis-1:trans-1 mixture. Reaction of C[sub 5]H[sub 5](CO)[sub 2]Re([mu]-H)Pt(H)(PPh[sub 3])[sub 2] (3-Ph) with diphenylacetylene at [minus]9[degrees]C initially produced an 84:16 cis-1:trans-1 mixture. Photolysis of trans-1 in a methylcyclohexane glass at 10 K gave a 40:60 cis-1:trans-1 photostationary state. cis-C[sub 5]H[sub 5](CO)[sub 2]ReHD (cis-1-HD) has an unusual intermediate magnitude of J[sub HD] = 6.5 Hz, which suggested the possibility that cis-1 might be in equilibrium with C[sub 5]H[sub 5](CO)[sub 2]Re([eta][sup 2]-HD) (cis-1-[eta][sup 2]-HD). Howevr, it was not possible to detect measurable amounts of C[sub 5]H[sub 5](CO)[sub 2]Re([eta][sup 2]-H[sub 2]) (cis-1-[eta][sup 2]-H[sub 2]) by IR spectroscopy. 30 refs., 1 fig., 2 tabs.
OSTI ID:
6724601
Journal Information:
Inorganic Chemistry; (United States), Journal Name: Inorganic Chemistry; (United States) Vol. 31:26; ISSN 0020-1669; ISSN INOCAJ
Country of Publication:
United States
Language:
English

Similar Records

First examples of homogeneous hydrogenolysis of thiophene to 1-butanethiolate and ethylthioketene ligands: Synthesis and reactivity of ([eta][sup 4]-C[sub 4]H[sub 5]S)ReH[sub 2](PPh[sub 3])[sub 2]
Journal Article · Tue Dec 29 23:00:00 EST 1992 · Journal of the American Chemical Society; (United States) · OSTI ID:6305007
The fate of a bimetallic ethylene dimerization catalyst: Synthesis and structure of (dfepe){sub 2}Ir{sub 2}({mu}-{eta}{sup 1}:{eta}{sup 3}-C{sub 4}H{sub 6})({mu}-H)(H) (dfepe = (C{sub 2}F{sub 5}){sub 2}PCH{sub 2}CH{sub 2}P(C{sub 2}F{sub 5}){sub 2})
Journal Article · Sun Dec 19 23:00:00 EST 1999 · Organometallics · OSTI ID:20013626
Heterometallic analogues of ((. eta. sup 5 -C sub 5 Me sub 5 )M(CO) sub 2 ) sub 2 (M = Fe, Ru, Os). Synthesis and structures of (. eta. sup 5 -C sub 5 Me sub 5 ) sub 2 (CO) sub 4 IrRe, (. eta. sup 5 -C sub 5 Me sub 5 ) sub 2 (CO) sub 4 IrMn, and (. eta. sup 5 -C sub 5 Me sub 5 )(. eta. sup 5 -C sub 5 H sub 5 )(CO) sub 4 IrRe
Journal Article · Mon Oct 01 00:00:00 EDT 1990 · Organometallics; (United States) · OSTI ID:5943495

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400500 -- Photochemistry
ALKENES
CARBONYLS
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CYCLOALKENES
CYCLOPENTADIENE
DECOMPOSITION
DEUTERIUM COMPOUNDS
DIENES
EQUILIBRIUM
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
ISOMERS
KINETICS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
POLYENES
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
RHENIUM COMPOUNDS
RHENIUM HYDRIDES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS