Metal-metal bonds involving the f-element. 2. Nature of the bonding in (eta/sup 5/-C/sub 5/H/sub 5/)/sub 2/(I)M-Ru(eta/sup 5/-C/sub 5/H/sub 5/)(CO)/sub 2/ (M = Zr, Th) complexes
Conference
·
· J. Am. Chem. Soc.; (United States)
OSTI ID:6613749
The chemistry of organoactinide complexes which contain a direct metal-metal bond between an actinide atom and a transition metal is currently of great interest. The authors have found that the bonding of the RuCp(CO)/sub 2/ fragment to either a Cp/sub 2/(X)Zr or a Cp*/sub 2/(X)Th fragment is not remarkably different from the bonding of other formally anionic ligands (such as halides or alkyls) to the same fragments. In this regard, they feel that RuCp(CO)/sub 2/ can be regarded as an organometallic pseudohalide in these heterobimetallic complexes, a notion which is certainly consistent with the synthetic pathways to the complexes.
- Research Organization:
- Ohio State Univ., Columbus
- DOE Contract Number:
- FG02-86ER13529
- OSTI ID:
- 6613749
- Journal Information:
- J. Am. Chem. Soc.; (United States), Vol. 109:3
- Country of Publication:
- United States
- Language:
- English
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Metal-metal multiple bonds. 20. Structural, kinetic, and theoretical studies of the reactivity of dimolybdenum. mu. -alkylidenes toward small molecules. Structures of M/sub 2/(. mu. -CAr/sub 2/), M/sub 2/(. mu. -CAr/sub 2/'), and M/sub 2/(. mu. -eta/sup 1/,eta/sup 2/-i-PrNC = CAr/sub 2/') (M = Cp(or Cp')Mo(CO)/sub 2/, Ar = p-Tolyl, Ar/sub 2/' = 2,2'-biphenylenyl, and Cp' = C/sub 5/H/sub 4/Me)
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Mon Oct 01 00:00:00 EDT 1990
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·
OSTI ID:6613749
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Metal-metal multiple bonds. 20. Structural, kinetic, and theoretical studies of the reactivity of dimolybdenum. mu. -alkylidenes toward small molecules. Structures of M/sub 2/(. mu. -CAr/sub 2/), M/sub 2/(. mu. -CAr/sub 2/'), and M/sub 2/(. mu. -eta/sup 1/,eta/sup 2/-i-PrNC = CAr/sub 2/') (M = Cp(or Cp')Mo(CO)/sub 2/, Ar = p-Tolyl, Ar/sub 2/' = 2,2'-biphenylenyl, and Cp' = C/sub 5/H/sub 4/Me)
Journal Article
·
Wed Jun 10 00:00:00 EDT 1987
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6613749
+3 more
Reaction of sulfur dioxide with (eta/sup 5/-C/sub 5/Me/sub 5/)Ru(CO)/sub 2/H: insertion of SO/sub 2/ into the Ru-H bond and oxygen transfer to form (eta/sup 5/-C/sub 5/Me/sub 5/)Ru(CO/sub 2/)SO/sub 3/H
Journal Article
·
Fri Jul 01 00:00:00 EDT 1988
· Organometallics; (United States)
·
OSTI ID:6613749
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBONYLS
BINDING ENERGY
CHEMICAL BONDS
ORGANIC IODINE COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPLEXES
THORIUM COMPLEXES
ZIRCONIUM COMPLEXES
MOLECULAR MODELS
MOLECULAR ORBITAL METHOD
MOLECULAR STRUCTURE
THEORETICAL DATA
ACTINIDE COMPLEXES
COMPLEXES
DATA
ENERGY
INFORMATION
MATHEMATICAL MODELS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBONYLS
BINDING ENERGY
CHEMICAL BONDS
ORGANIC IODINE COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPLEXES
THORIUM COMPLEXES
ZIRCONIUM COMPLEXES
MOLECULAR MODELS
MOLECULAR ORBITAL METHOD
MOLECULAR STRUCTURE
THEORETICAL DATA
ACTINIDE COMPLEXES
COMPLEXES
DATA
ENERGY
INFORMATION
MATHEMATICAL MODELS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties