Rate constant for the reaction of OH with HO/sub 2/

Journal Article · Tue Jan 01 04:00:00 EST 1980 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100445a003· OSTI ID:6611956

Lii, R R; Gorse, Jr, R A; Sauer, Jr, M C; Gordon, S

Spectrophotometric observation of both HO/sub 2/ and OH in pulse-irradiated Ar-H/sub 2/O-O/sub 2/ systems leads to a value of k/sub 1/ = (0.99 +- 0.12) x 10/sup -10/ cm/sup 3/ molecule/sup -1/s/sup -1/ at 308 K for the reaction OH + HO/sub 2/ ..-->.. H/sub 2/O + O/sub 2/.

• Research Organization: Argonne National Lab., IL
• OSTI ID: 6611956
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 84:8; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
ARGON
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DECOMPOSITION
ELEMENTS
FLUIDS
GASES
HYDROGEN COMPOUNDS
HYDROPEROXY RADICALS
HYDROXYL RADICALS
IRRADIATION
KINETICS
LOW PRESSURE
MEDIUM PRESSURE
MEDIUM TEMPERATURE
NONMETALS
OXYGEN
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
PULSED IRRADIATION
RADICALS
RARE GASES
REACTION KINETICS
SPECTROPHOTOMETRY
WATER