Rate constant of the reaction of O(/sup 3/P) with HO/sub 2/

Journal Article · Tue Jan 01 04:00:00 EST 1980 · J. Phys. Chem.; (United States)

OSTI ID:6611618

Ruey-Rong, L; Sauer, Jr, M C; Gordon, S

The rate constant for the reaction of O(/sup 3/P) with HO/sub 2/ is measured at 298 K by spectrophotometric observation of the HO/sub 2/ decay (230 nm) and the O/sub 3/ formation (265 nm) following irradiation of systems of ca. 3.6 x 10/sup 19/ molecules of Ar cm/sup -3/, 6.5 x 10/sup 18/ molecules of H/sub 2/ cm/sup -3/, and 1.6 x 10/sup 18/-6.5 x 10/sup 18/ molecules of O/sub 2/ cm/sup -3/ with electron pulses. The rate constant obtained is (7 +- 2) x 10/sup -11/ cm/sup 3/ molecule/sup -1/s/sup -1/.

• Research Organization: Argonne National Lab., IL
• OSTI ID: 6611618
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 84:8; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ARGON
BEAMS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
ELECTRON BEAMS
ELEMENTS
FLUIDS
GASES
HYDROGEN
HYDROPEROXY RADICALS
IRRADIATION
KINETICS
LEPTON BEAMS
LOW PRESSURE
MEDIUM PRESSURE
MEDIUM TEMPERATURE
NONMETALS
OXYGEN
OZONE
PARTICLE BEAMS
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOLYSIS
RARE GASES
REACTION KINETICS
SPECTROPHOTOMETRY