Rate constant of the reaction of O(/sup 3/P) with HO/sub 2/

Journal Article · Thu Apr 17 04:00:00 EST 1980 · J. Phys. Chem.; (United States)

OSTI ID:5252383

Lii, Ruey-Rong; Sauer, Jr, M C; Gordon, S

The rate contant for the reaction of O(/sup 3/P) with HO/sub 2/ is measured at 298 K by spectrophotometric observation of the HO/sub 2/ decay (230 nm) and the O/sub 3/ formation (265 nm) following irradiation of systems of ca. 3.6 x 10/sup 19/ molecules of Ar cm/sup -3/, 6.5 x 10/sup 18/ molecules of H/sub 2/ cm/sup -3/, and 1.6 x 10/sup 18/-6.5 x 10/sup 18/ molecules of O/sub 2/ cm/sup -3/ with electron pulses. The rate constant obtained is (7 +- 2) x 10/sup -11/ cm/sup 3/ molecule/sup -1/ s/sup -1/.

• Research Organization: Argonne National Lab., IL
• OSTI ID: 5252383
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 84:8; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ATOMS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
CRYOGENIC FLUIDS
DATA
DATA FORMS
ELECTRONS
ELEMENTARY PARTICLES
ELEMENTS
EXPERIMENTAL DATA
FERMIONS
FLUIDS
HYDROPEROXY RADICALS
INFORMATION
IRRADIATION
ISOLATED VALUES
KINETICS
LEPTONS
NONMETALS
NUMERICAL DATA
OXYGEN
OZONE
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
REACTION KINETICS
YIELDS