Electrode kinetics at a platinum anode in chloroacetic acid solutions

Journal Article · Sun Feb 01 00:00:00 EST 1987 · Sov. Electrochem. (Engl. Transl.); (United States)

OSTI ID:6558545

Lotvin, B M; Vasil'ev, Yu B

It was shown by direct comparison of kinetic and adsorption data that at platinum in solutions of mono- and trichloroacetic acid, the anodic processes are entirely analogous in character to the processes occurring in acetate solutions. The lack of Kolbe electrosynthesis products in the electrolysis of chloroacetic acids is to the special reaction features of the secondary chloroalkyl radicals.

• Research Organization: A.N. Frumkin Institute of Electrochemistry, Moscow, USSR
• OSTI ID: 6558545
• Journal Information: Sov. Electrochem. (Engl. Transl.); (United States), Vol. 22:8; Other Information: Translated from Elektrokhimiya; 22: No. 8, 1029-1033(Aug 1986)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ACETATES
ELECTROLYSIS
OXIDATION
ACETIC ACID
ORGANIC CHLORINE COMPOUNDS
PLATINUM
CATALYTIC EFFECTS
ADSORPTION
CARBON DIOXIDE
CHEMICAL REACTION KINETICS
DESORPTION
ELECTROCATALYSTS
ELECTROCHEMISTRY
OVERVOLTAGE
OXYGEN
PH VALUE
POLARIZATION
POTENTIOMETRY
CARBON COMPOUNDS
CARBON OXIDES
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CATALYSTS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
ELEMENTS
KINETICS
LYSIS
METALS
MONOCARBOXYLIC ACIDS
NONMETALS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
REACTION KINETICS
SORPTION
TITRATION
TRANSITION ELEMENTS
400400* - Electrochemistry
400201 - Chemical & Physicochemical Properties