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Electrode kinetics at a platinum anode in chloroacetic acid solutions

Journal Article · · Sov. Electrochem. (Engl. Transl.); (United States)
OSTI ID:6558545
It was shown by direct comparison of kinetic and adsorption data that at platinum in solutions of mono- and trichloroacetic acid, the anodic processes are entirely analogous in character to the processes occurring in acetate solutions. The lack of Kolbe electrosynthesis products in the electrolysis of chloroacetic acids is to the special reaction features of the secondary chloroalkyl radicals.
Research Organization:
A.N. Frumkin Institute of Electrochemistry, Moscow, USSR
OSTI ID:
6558545
Journal Information:
Sov. Electrochem. (Engl. Transl.); (United States), Journal Name: Sov. Electrochem. (Engl. Transl.); (United States) Vol. 22:8; ISSN SOECA
Country of Publication:
United States
Language:
English