Influence of carboxylic-acid structure on the kinetics of electrode processes occurring during Kolbe electrosynthesis
Journal Article
·
· Sov. Electrochem. (Engl. Transl.); (United States)
OSTI ID:6449847
The influence of carboxylic-acid structure on the kinetics of electrode processes occurring during Kolbe electrosynthesis was studied, and shown to produce changes in the rates of destructive chemisorption and destructive oxidation of the carboxylic acid, in the competition for the platinum electrode surface between the solvent and the carboxylate anions at high anode potentials, and in the routes of radical reactions because of changes in the nature of the radical formed.
- Research Organization:
- All-Union Scientific-Research Institute of Medicinal Chemistry and Technology, Kharkov, USSR
- OSTI ID:
- 6449847
- Journal Information:
- Sov. Electrochem. (Engl. Transl.); (United States), Journal Name: Sov. Electrochem. (Engl. Transl.); (United States) Vol. 22:8; ISSN SOECA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400400* -- Electrochemistry
CARBOXYLIC ACIDS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISORPTION
CHEMISTRY
ELECTROCATALYSTS
ELECTROCHEMISTRY
ELECTRODES
ELECTROLYSIS
ELEMENTS
KINETICS
LYSIS
METALS
MOLECULAR STRUCTURE
ORGANIC ACIDS
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
OXIDATION
PLATINUM
PLATINUM METALS
POLARIZATION
REACTION KINETICS
SEPARATION PROCESSES
SORPTION
TRANSITION ELEMENTS
400201 -- Chemical & Physicochemical Properties
400400* -- Electrochemistry
CARBOXYLIC ACIDS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISORPTION
CHEMISTRY
ELECTROCATALYSTS
ELECTROCHEMISTRY
ELECTRODES
ELECTROLYSIS
ELEMENTS
KINETICS
LYSIS
METALS
MOLECULAR STRUCTURE
ORGANIC ACIDS
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
OXIDATION
PLATINUM
PLATINUM METALS
POLARIZATION
REACTION KINETICS
SEPARATION PROCESSES
SORPTION
TRANSITION ELEMENTS