Selectivity of catalytic oxidation of aliphatic aldehydes
Journal Article
·
· Pet. Chem. USSR (Engl. Transl.); (United States)
Results of studies of the catalytic oxidation of n-butyraldehyde in a methylacetate solution are reported. Oxidation of butyraldehyde with pure oxygen produced perbutyric and butyric acid in the presence of cobalt, manganese, copper, chromium, molybdenum, and vanadyl stearate. The reaction mechanism remainded the same regardless of the cation, but differences in activity and selectivity were determined by the type of metal cation. In the presence of a mixture of transition metal salts, i.e., cobalt-copper butyrates, control of product composition was possible by controlling the concentration of oxygen in the oxidizing gas. (BLM)
- Research Organization:
- D.I. Mendeleyev Chemico-Technological Inst., Moscow, USSR
- OSTI ID:
- 6533899
- Journal Information:
- Pet. Chem. USSR (Engl. Transl.); (United States), Journal Name: Pet. Chem. USSR (Engl. Transl.); (United States) Vol. 19:3; ISSN PECHA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Activity of catalysts in the initial stage of oxidation of isomeric xylenes by molecular oxygen
High temperature methanation with molten salt-based catalyst systems. [molten halide or carbonate carrier with catalytically active metals, metal oxides or carbides dispensed in it]
Exchange of molecular oxygen with the oxygen of some metal molybdates used as catalysts for selective oxidation
Journal Article
·
Tue Sep 20 00:00:00 EDT 1988
· J. Appl. Chem. USSR (Engl. Transl.); (United States)
·
OSTI ID:6084568
High temperature methanation with molten salt-based catalyst systems. [molten halide or carbonate carrier with catalytically active metals, metal oxides or carbides dispensed in it]
Patent
·
Tue Aug 30 00:00:00 EDT 1977
·
OSTI ID:7081401
Exchange of molecular oxygen with the oxygen of some metal molybdates used as catalysts for selective oxidation
Journal Article
·
Mon Oct 15 00:00:00 EDT 1979
· J. Catal.; (United States)
·
OSTI ID:6462714
Related Subjects
01 COAL, LIGNITE, AND PEAT
014000 -- Coal
Lignite
& Peat-- Combustion
02 PETROLEUM
025000 -- Petroleum-- Combustion
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALDEHYDES
BUTYRIC ACID
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHROMIUM COMPOUNDS
COBALT COMPOUNDS
COPPER COMPOUNDS
DATA
EXPERIMENTAL DATA
GRAPHS
INFORMATION
MANGANESE COMPOUNDS
MOLYBDENUM COMPOUNDS
MONOCARBOXYLIC ACIDS
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXIDATION
STEARATES
TABLES
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
014000 -- Coal
Lignite
& Peat-- Combustion
02 PETROLEUM
025000 -- Petroleum-- Combustion
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALDEHYDES
BUTYRIC ACID
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHROMIUM COMPOUNDS
COBALT COMPOUNDS
COPPER COMPOUNDS
DATA
EXPERIMENTAL DATA
GRAPHS
INFORMATION
MANGANESE COMPOUNDS
MOLYBDENUM COMPOUNDS
MONOCARBOXYLIC ACIDS
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXIDATION
STEARATES
TABLES
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS