(BEDO) sub 2. 4 I sub 3 : The first robust organic metal of BEDO-TTF
Journal Article
·
· Journal of the American Chemical Society; (USA)
- Univ. of California, Santa Barbara (USA)
- State Univ. of New York, Buffalo (USA)
The design of electron donors for metallic and superconducting organic solids requires the incorporation of a large number of increasingly polarizable elements such as S, Se, and Te. Contrary to this dictum, the authors designed the new donor BEDO-TTF (1, aka BEDO), which has oxygen substituents. Here they present results on a BEDO salt that indicates that, contrary to the above, oxygen substitution can increase the metallic bandwidth, thus stabilizing the metallic state down to low temperature and producing an organic solid that is akin to a typical inorganic metal in its transport and magnetic properties.
- OSTI ID:
- 6518550
- Journal Information:
- Journal of the American Chemical Society; (USA), Journal Name: Journal of the American Chemical Society; (USA) Vol. 112:6; ISSN 0002-7863; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Wed May 02 00:00:00 EDT 1990
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·
OSTI ID:6667885
A hybrid material based on [Mo{sub 6}Br{sub 14}]{sup 2-} inorganic cluster units and [BEDO-TTF]{sup +} organic monocationic radicals: Synthesis, structure and properties of (BEDO-TTF){sub 2}Mo{sub 6}Br{sub 14}(PhCN){sub 4}
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
DATA
DATA ANALYSIS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN ADDITIONS
PHYSICAL PROPERTIES
SUPERCONDUCTIVITY
SYNTHESIS
400201* -- Chemical & Physicochemical Properties
DATA
DATA ANALYSIS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN ADDITIONS
PHYSICAL PROPERTIES
SUPERCONDUCTIVITY
SYNTHESIS