A hybrid material based on [Mo{sub 6}Br{sub 14}]{sup 2-} inorganic cluster units and [BEDO-TTF]{sup +} organic monocationic radicals: Synthesis, structure and properties of (BEDO-TTF){sub 2}Mo{sub 6}Br{sub 14}(PhCN){sub 4}
- UMR CNRS 6226 'Sciences Chimiques de Rennes', Universite de Rennes 1, Campus de Beaulieu (Bat. 10A), Avenue du General Leclerc, 35042 Rennes Cedex (France)
- Organic Solid State Chemistry, Division of Chemistry, Graduate School of Science, Kyoto University, Oiwake-cho, Kitashirakawa, Sakyo-ku, Kyoto, 606-8502 (Japan)
The first charge transfer salt based on non-dimerized [BEDO-TTF]{sup +} monocationic radical (BEDO-TTF=bis(ethylenedioxy)tetrathiafulvalene) associated with [Mo{sub 6}Br{sub 14}]{sup 2-} cluster anions has been synthesized by conventional electro-oxidation and characterized by single crystal X-ray diffraction, UV-VIS-NIR absorption and magnetic susceptibility measurements. (BEDO-TTF){sub 2}Mo{sub 6}Br{sub 14}(PhCN){sub 4} crystallizes in the monoclinic system, space group P2{sub 1}/n, a=10.414(4)A, b=21.711(7)A, c=15.958(5)A, {beta}=93.65(3){sup o}, V=3601(2)A{sup 3}, Z=2, R{sub 1}=0.0578, wR{sub 2}=0.0731. The structure of this hybrid compound is built up from a [BEDO-TTF]{sup +} and PhCN (benzonitrile) organic framework in which are hosted the [Mo{sub 6}Br{sub 14}]{sup 2-} inorganic cluster units. It results in non- dimerized [BEDO-TTF]{sup +} cations that exhibit a paramagnetic behavior characteristic of one unpaired electron.
- OSTI ID:
- 20900902
- Journal Information:
- Journal of Solid State Chemistry, Vol. 179, Issue 12; Other Information: DOI: 10.1016/j.jssc.2006.07.030; PII: S0022-4596(06)00427-0; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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