The first ambient pressure organic superconductor containing oxygen in the donor molecule,. beta. sub m -(BEDO-TTF) sub 3 Cu sub 2 (NCS) sub 3 , T sub c = 1. 06 K
Journal Article
·
· Inorganic Chemistry; (USA)
- Argonne National Lab., IL (USA)
- North Carolina State Univ., Raleigh (USA)
The discovery of superconductivity in an organic charge-transfer salt containing an oxygen-bearing organic-donor molecule is reported. The synthesis of the compound, {beta}{sub m}-(BEDO-TTF){sub 3}Cu{sub 2}(NCS){sub 3} BEDO-TTF = bis(ethylenedioxy) tetrafulvalene, is described. Its crystal structure, its characteristic ESR properties, results of inductive measurements of its superconducting transition, and its band electronic structure are all reported. 18 refs., 3 figs.
- DOE Contract Number:
- W-31-109-ENG-38; FG05-86ER45259
- OSTI ID:
- 6667885
- Journal Information:
- Inorganic Chemistry; (USA), Vol. 29:9; ISSN 0020-1669
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
COPPER COMPOUNDS
SUPERCONDUCTIVITY
ETHYLENE
ORGANIC OXYGEN COMPOUNDS
THIOCYANATES
TTF
CHEMICAL PREPARATION
ELECTRONIC STRUCTURE
EXPERIMENTAL DATA
ALKENES
ANTITHYROID DRUGS
CARBONIC ACID DERIVATIVES
DATA
DRUGS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
HETEROCYCLIC COMPOUNDS
HORMONE ANTAGONISTS
HYDROCARBONS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHYSICAL PROPERTIES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
360601* - Other Materials- Preparation & Manufacture
360603 - Materials- Properties
COPPER COMPOUNDS
SUPERCONDUCTIVITY
ETHYLENE
ORGANIC OXYGEN COMPOUNDS
THIOCYANATES
TTF
CHEMICAL PREPARATION
ELECTRONIC STRUCTURE
EXPERIMENTAL DATA
ALKENES
ANTITHYROID DRUGS
CARBONIC ACID DERIVATIVES
DATA
DRUGS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
HETEROCYCLIC COMPOUNDS
HORMONE ANTAGONISTS
HYDROCARBONS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHYSICAL PROPERTIES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
360601* - Other Materials- Preparation & Manufacture
360603 - Materials- Properties