Electronic structures of the transition metal carbides and borides studied by x-ray photoelectron spectroscopy and band calculation
Technical Report
·
OSTI ID:6515906
Previous band models of the transition metal carbides and borides are reviewed. The atomic structures of transition metal carbides (TiC, ZrC, HfC, VC, NbC and TaC), borides (TiB/sub 2/ and ZrB/sub 2/), and some related materials (Ti, Zr, CaB/sub 6/ and LaB/sub 6/) are studied by the interplay between X-ray photoelectron spectroscopy (XPS) and augmented plane wave (APW) calculation. Topics covered include the following: (1) APW band calculation and results; (2) XPS study of the densities of state; (3) band structures and related physical properties; (4) chemical shifts and charge transfer; and (5) application of the transition metal carbides to the solar selective surface.
- Research Organization:
- Electrotechnical Lab., Tokyo (Japan)
- OSTI ID:
- 6515906
- Report Number(s):
- N-78-23968
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360104 -- Metals & Alloys-- Physical Properties
360204* -- Ceramics
Cermets
& Refractories-- Physical Properties
ALKALINE EARTH METAL COMPOUNDS
BAND THEORY
BORIDES
BORON COMPOUNDS
CALCIUM BORIDES
CALCIUM COMPOUNDS
CARBIDES
CARBON COMPOUNDS
CHEMICAL SHIFT
ELECTRON SPECTROSCOPY
ELECTRONIC STRUCTURE
ELEMENTS
ENERGY-LEVEL DENSITY
HAFNIUM CARBIDES
HAFNIUM COMPOUNDS
LANTHANUM BORIDES
LANTHANUM COMPOUNDS
METALS
NIOBIUM CARBIDES
NIOBIUM COMPOUNDS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
RARE EARTH COMPOUNDS
SPECTRALLY SELECTIVE SURFACES
SPECTROSCOPY
SURFACES
TANTALUM CARBIDES
TANTALUM COMPOUNDS
TITANIUM
TITANIUM BORIDES
TITANIUM CARBIDES
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
VANADIUM CARBIDES
VANADIUM COMPOUNDS
ZIRCONIUM BORIDES
ZIRCONIUM CARBIDES
ZIRCONIUM COMPOUNDS
360104 -- Metals & Alloys-- Physical Properties
360204* -- Ceramics
Cermets
& Refractories-- Physical Properties
ALKALINE EARTH METAL COMPOUNDS
BAND THEORY
BORIDES
BORON COMPOUNDS
CALCIUM BORIDES
CALCIUM COMPOUNDS
CARBIDES
CARBON COMPOUNDS
CHEMICAL SHIFT
ELECTRON SPECTROSCOPY
ELECTRONIC STRUCTURE
ELEMENTS
ENERGY-LEVEL DENSITY
HAFNIUM CARBIDES
HAFNIUM COMPOUNDS
LANTHANUM BORIDES
LANTHANUM COMPOUNDS
METALS
NIOBIUM CARBIDES
NIOBIUM COMPOUNDS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
RARE EARTH COMPOUNDS
SPECTRALLY SELECTIVE SURFACES
SPECTROSCOPY
SURFACES
TANTALUM CARBIDES
TANTALUM COMPOUNDS
TITANIUM
TITANIUM BORIDES
TITANIUM CARBIDES
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
VANADIUM CARBIDES
VANADIUM COMPOUNDS
ZIRCONIUM BORIDES
ZIRCONIUM CARBIDES
ZIRCONIUM COMPOUNDS