Telomerization of isoprene with n-methylaniline on complex palladium catalysts

Journal Article · Fri Dec 19 23:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00956601· OSTI ID:6477123

Zakharkin, L I; Petrushkina, E A

In the telomerization of isoprene with N-methylaniline on complex palladium catalysts, a mixture of N-methyl-N-(2,7-; 2,6-; 3,7-; 3,6-dimethyloctadien-2,7-yl)anilines is obtained, and their ratio is dependent on the solvent and composition of the catalyst. 1-Iododimethyl-2,7-octadienes and trimethylphenylammonium iodide are formed under the effect of MeI on a mixture of N-methyl-N-(dimethyloctadien-2,7-yl)anilines. The Pd(OAc)/sub 2/-Ph/sub 3/P catalytic system causes deamination of N-methyl-N-(dimethyl-octadien-2,7-yl)anilines on heating with the formation of dimethyl-1,3,7-octatrienes and N-methylaniline.

• Research Organization: A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow, USSR
• OSTI ID: 6477123
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:6; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETATES
ACETONITRILE
ACETYLACETONE
ADDUCTS
ALCOHOLS
AMINES
AMMONIUM COMPOUNDS
AMMONIUM HALIDES
ANILINE
AROMATICS
CARBOXYLIC ACID SALTS
CATALYSTS
CATALYTIC EFFECTS
CHELATING AGENTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
CHROMATOGRAPHY
COMPLEXES
DEAMINATION
DIENES
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROXY COMPOUNDS
IODINATED ALIPHATIC HYDROCARBONS
ISOPRENE
KETONES
METHANOL
METHYL IODIDE
NITRILES
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
POLYENES
POLYMERIZATION
REAGENTS
SEPARATION PROCESSES
SPECTRA
SYNTHESIS
TELOMERIZATION
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS