Telomerization of isoprene with phthalimide at complex palladium catalysts

Journal Article · Sat Jan 09 23:00:00 EST 1988 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6420676

Zakharkin, M I; Guseva, V V; Sulaimankulova, D D; Petrushkina, E A

The telomerization of isoprene with phthalimide takes place smoothly at complex palladium catalysts with the formation of a mixture of N-dimethyloctadienyl-phthalimides, which give a mixture of seven dimethyloctadienylamines when treated with hydrazine. By comparison of the samples of all the mixtures of N-dimethyloctadienyldimethylamines by GLC we established that terpene amines are formed during the telomerization of isoprene with phthalimide followed by cleavage of the mixture of telomers with hydrazine hydrate.

• OSTI ID: 6420676
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 23:8; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
AMIDES
AMINES
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPLEXES
DIENES
HYDRAZINE
HYDROCARBONS
IMIDES
ISOPRENE
NITROGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PALLADIUM COMPLEXES
POLYENES
POLYMERIZATION
POTASSIUM COMPOUNDS
SEPARATION PROCESSES
STRUCTURAL CHEMICAL ANALYSIS
TELOMERIZATION
TRANSITION ELEMENT COMPLEXES