Bromination of 1,5-dimethylnaphthalene in the presence of iron

Journal Article · Sat Jun 20 00:00:00 EDT 1987 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6034292

Pozdnyakovich, S A; Shigalevskii, V A; Pozdnyakovich, Yu V

The reaction of 1,5-dimethylnaphthelene with bromine in the presence of iron powder leads to the formation of 2-, 3-, and 4-bromo-1,5-dimethylnaphthalenes and 2,6-, 2,7-, and 3,7-dibromo-1,5-dimethylnaphthalenes, the ratios of which depend on the amount of catalyst. The contents of 2-bromo-1,5-dimethyl-naphthalene and 2,6-dibromo-1,5-dimethylnaphthalene in the mixture of products increase with decrease in the amount of catalyst.

• OSTI ID: 6034292
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 23:1; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
AROMATICS
BROMINATED AROMATIC HYDROCARBONS
BROMINATION
CARBON 13
CARBON ISOTOPES
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
CONDENSED AROMATICS
DEUTERIUM COMPOUNDS
ELEMENTS
EVEN-ODD NUCLEI
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATED AROMATIC HYDROCARBONS
HALOGENATION
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROGEN TRANSFER
HYPERFINE STRUCTURE
INFRARED SPECTRA
IRON
ISOMERIZATION
ISOMERS
ISOTOPES
LIGHT NUCLEI
LINE BROADENING
METALS
NAPHTHALENE
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
QUANTITY RATIO
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TRANSITION ELEMENTS