Generalizations of the Stern-Volmer relation

Journal Article · Thu Jan 07 04:00:00 EST 1993 · Journal of Physical Chemistry; (United States)

DOI:https://doi.org/10.1021/j100103a034· OSTI ID:6442638

Green, N J.B. ^[1]; Pimblott, S M ^[2]; Tachiya, M ^[3]

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1. King's College, London (United Kingdom)
2. Univ. of Notre Dame, IN (United States)
3. National Chemical Laboratory for Industry, Ibaraka (Japan)

The Stern-Volmer analysis is an elementary method of photochemistry and is discussed in many standard physical chemistry texts. This relationship of photochemistry is generalized to describe systems in which the decay under investigation is nonexponential and systems in which the quenching or scavenging is inherently transient and must be described with a time-dependent rate constant. 39 refs.

• OSTI ID: 6442638
• Journal Information: Journal of Physical Chemistry; (United States), Journal Name: Journal of Physical Chemistry; (United States) Vol. 97:1; ISSN JPCHAX; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
CHEMISTRY
DECAY
KINETICS
MATHEMATICAL MODELS
PHOTOCHEMISTRY
QUENCHING
SCAVENGING
TIME DEPENDENCE