/sup 13/C NMR spectra of organic peroxides

Journal Article · Tue Aug 10 00:00:00 EDT 1982 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00948235· OSTI ID:6441039

Aganov, A V; Antonovskii, V L

A study has been made of the /sup 13/C NMR spectra of hydroperoxides, peroxides, peroxy esters, and diacyl peroxides. Results indicated that the signal of the carbon atoms of a hydrocarbon radical present in the ..cap alpha..-position relative to the peroxide group is shifted downfield in comparison with the nonperoxide analog. The replacement of -O- by an -OO- group at a carbonyl carbon produces an upfield shift of the signal from this atom.

• Research Organization: Academy of Sciences of the USSR, Moscow
• OSTI ID: 6441039
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 31:2; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CARBON 13
CARBON ISOTOPES
CHEMICAL SHIFT
EVEN-ODD NUCLEI
ISOTOPES
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PEROXIDES
SPECTRA
STABLE ISOTOPES