/sup 13/C NMR spectroscopy of peroxide derivatives of cyclanes and cyclic peroxides

Journal Article · Mon Aug 10 00:00:00 EDT 1987 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00959364· OSTI ID:5846254

Klochkov, V V; Antonovskii, V L; Chernov, P P; Aganov, A V; Koshel', G N

The /sup 13/C NMR spectra of peroxide derivatives of cyclanes and cyclic peroxides have been investigated. Replacement of the exocyclic OH group by OOH for saturated cyclic systems leads to a displacement of the signals from the ..cap alpha..-carbon downfield by 13.0 ppm, while the ..beta..-carbon is displaced upfield by 4.5 ppm, without any dependence on the size or conformational structure of the rings. Replacement of the transannular OO group by CH/sub 2/CH/sub 2/ or CH/sub 2/O increases the shielding of the quaternary carbon adjoining it.

• Research Organization: Institute of Chemical Physics, Moscow, USSR
• OSTI ID: 5846254
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 36:2; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
CARBON 13
CARBON ISOTOPES
CHEMICAL SHIFT
CONFORMATIONAL CHANGES
CYCLOALKANES
ELECTRONEGATIVITY
ELECTRONIC STRUCTURE
EVEN-ODD NUCLEI
HEAVY WATER
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN TRANSFER
ISOTOPE EFFECTS
ISOTOPE RATIO
ISOTOPES
ISOTOPIC EXCHANGE
LIGHT NUCLEI
LINE BROADENING
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PEROXIDES
SPECTRA
STABLE ISOTOPES
WATER