Catalytic reaction of pi-allyl complexes of palladium with allyl O and N nucleophiles, a new promising route for synthesis of C/sub 16/ amines and ethers

Journal Article · Fri Jun 20 00:00:00 EDT 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:6416645

Fakhretdinov, R N; Telin, A G; Dzhemilev, U M

To develop efficient and promising methods for synthesis of scarce higher unsaturated amines and ethers, they investigated the reaction of tertiary 2,7-octadienylamines, butenyl amines of different structures, and 2,7-octadienyl ethers of aliphatic alcohols and esters of carboxylic acids with butadiene in the presence of Pd catalysts activated by electron-donor and electron-acceptor ligands. A new one-step method was developed for synthesis of polyunsaturated C/sub 16/ amines, ethers, and hydrocarbons with readily available reagents.

• Research Organization: Institute of Chemistry, Ufa, USSR
• OSTI ID: 6416645
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:12; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
AMINES
AZINES
BINDING ENERGY
BUTADIENE
BUTENES
CARBON 13
CARBON ISOTOPES
CARBOXYLIC ACID ESTERS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DIENES
ELECTRON SPIN RESONANCE
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
ESTERS
ETHERS
EVEN-ODD NUCLEI
FERMIONS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
INFRARED SPECTRA
ISOTOPES
LEPTONS
LIGHT NUCLEI
MAGNETIC RESONANCE
MASS SPECTRA
MOLECULAR STRUCTURE
MULTIPLETS
NMR SPECTRA
NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
PIPERIDINES
POLYENES
PYRIDINES
RESONANCE
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
VALENCE
YIELDS