Joint catalytic activation of CO/sub 2/ and NH/sub 3/ in reaction with butadiene under the action of palladium complexes
In a continuation of the study of catalytic reactions in which small molecules participate they have examined the reaction of butadiene simultaneously with CO/sub 2/ and NH/sub 3/ in the presence of homogeneous Pd-containing catalyst complexes with the object of developing a single-step method for the synthesis of unsaturated higher formamides. The possibility of joint catalytic activation of small molecules (CO/sub 2/ and NH/sub 3/) has been demonstrated in their reaction with butadiene with the participation of palladium complexes, the products being mono- and bis-(2,7-octadienyl)formamides. It has been found that 2-pyrrolidone can take part in a telomerization reaction with butadiene in solutions containing palladium complexes, ammonia and carbon dioxide with the formation of N-2,7-octadienylpyrrolidone.
- Research Organization:
- Institute of Chemistry, Ufa, USSR
- OSTI ID:
- 5675932
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 36:2; ISSN BACCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
AMIDES
AMMONIA
AZOLES
BUTADIENE
CARBON 13
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON ISOTOPES
CARBON OXIDES
CATALYSIS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL ACTIVATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
COMPLEXES
DIENES
ENERGY
EVEN-ODD NUCLEI
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROCARBONS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
ISOMERS
ISOTOPES
KINETICS
LACTAMS
LIGHT NUCLEI
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
OXIDES
OXYGEN COMPOUNDS
PALLADIUM COMPLEXES
POLYENES
POLYMERIZATION
PYRROLES
PYRROLIDONES
REACTION KINETICS
SOLVENTS
SPECTRA
STABLE ISOTOPES
TELOMERIZATION
TRANSITION ELEMENT COMPLEXES
YIELDS