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U.S. Department of Energy
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Efficacy of activated sludge/powdered activated carbon for removal of organic constituents in wastewater from commercial-scale, high-Btu coal gasification plant

Conference ·
OSTI ID:6400708
Bench-scale, activated-sludge (AS) treatability studies indicate that approximately 98 percent of total organic constituents can be removed from wastewater generated by HYGAS and slagging-type, high-Btu coal gasification pilot plants. This suggests that the most important unit of a wastewater treatment system for organics removal in commercial-scale versions of such plants will be the AS unit, augmented by powdered activated carbon (PAC) addition for control of refractory organics. The entire treatment train will probably have the configuration: API separator, phenol extraction, ammonia stripping, dissolved-air flotation, AS/PAC, and suspended solids separation. Taking the standard coal gasification plant as one producing 250 x 10/sup 6/ scfd of product gas, and the amount of quench and shift-condensate water delivered to the activated sludge unit as 2.8 MGD, the annual cost of removing organics by AS/PAC for such a commercial-scale plant is estimated at $2,500,000. The estimated annual energy impact for the equalization basin, the AS/PAC system, and for regeneration is estimated at 10.1 x 10/sup 6/ kWh(e), or 17.4 x 10/sup 3/ bbl crude oil equivalent. Together with the other process units in the overall treatment train, it is probable that the AS/PAC system can ensure environmental control of both major and trace organic constituents at acceptable levels. Additional bench-scale treatability studies should be conducted to confirm this supposition, however.
Research Organization:
Argonne National Lab., IL (USA); Engineering-Science, Inc., Austin, TX (USA)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
6400708
Report Number(s):
CONF-8006171-2; ON: DE81023575
Country of Publication:
United States
Language:
English