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Biological treatment of Hygas coal gasification wastewater

Technical Report ·
OSTI ID:5291460
An experimental study was performed to assess biological treatability characteristics of Hygas coal gasification process pilot plant wastewater comprised of cyclone and quench condensates. The study evaluated treatability characteristics of ammonia stripped and unstripped wastewater at full strength and at 1:1 dilution. It was determined that minimum pretreatment required for biological oxidation consisted of reducing wastewater alkalinity, and decreasing raw ammonia concentration by dilution or by stripping. Kinetic studies with stripped Hygas wastewater showed the waste could be processed at mean cell residence times varying from 10 to 40 days with hydraulic residence times of 2 to 3 days; the bacteriological yield coefficient was 0.11 (COD basis), and the decay coefficient was 0.02/day. The study also determined correlations for dissolved oxygen uptake, the effect of COD removal rate on zone settling velocity and sludge volume index, removal efficiencies for various constituents, and adsorption isotherms for biological effluent COD on activated carbon and process char. A literature review showed that there are differences in wastewater characteristics between coke plant weak ammonia liquors and high strength coal gasification process effluents. The available data base for design of coke plant biological treatment facilities is deficient; therefore, it is not possible to transfer other than general observations on biological treatment of coke plant effluents to biological treatment of coal gasification process effluents.
Research Organization:
Carnegie-Mellon Univ., Pittsburgh, PA (USA). Dept. of Civil Engineering
DOE Contract Number:
EX-76-S-01-2496
OSTI ID:
5291460
Report Number(s):
FE-2496-43
Country of Publication:
United States
Language:
English