Chain transfer in low-temperature liquid-phase oxidation reaction of hexafluoropropylene by molecular oxygen

Journal Article · Wed Jun 01 00:00:00 EDT 1988 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6289144

Shapovalov, V V; Poluektov, V A

The influence of the concentrations of hexafluoropropylene and oxygen, as well as of the rate of initiation of the initial reaction centers on the degree of polymerization of hexafluoropropylene were studied. A chain transfer mechanism was proposed for the reaction of peroxy radicals RO/sub 2//sup ./ + RO/sub 2//sup ./.

• OSTI ID: 6289144
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 28:6; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DISSOCIATION
ELEMENTS
FLUORINATED ALIPHATIC HYDROCARBONS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
KINETICS
NONMETALS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDATION
OXYGEN
OXYGEN COMPOUNDS
PEROXIDES
PEROXY RADICALS
POLYMERIZATION
PROPYLENE
QUANTITY RATIO
RADICALS
REACTION KINETICS
REDOX POTENTIAL