The mechanism of formation of hexafluoropropylene oxide upon radiation-induced oxidation of hexafluoropropylene
Journal Article
·
· High Energy Chemistry
OSTI ID:135992
- Karpov Institute of Physical Chemistry, Obninsk (Russian Federation)
Dependence of the formation rate of hexafluoropropylene oxide on oxygen pressure at 273 and 303 K was studied. It was shown that this dependence is almost inversely proportional. Experimental data confirm the conclusion that the epoxy is formed not in the commonly known reaction R-O-O-C{sub 3}F{sup {center_dot}}{sub 6} {r_arrow} RO{sup {center_dot}}+C{sub c}F{sub 6}O, but rather, in the reaction R-O-C{sub 3}F{sup {center_dot}}{sub 6} {r_arrow} R{sup {center_dot}}+C{sub 3}F{sub 6}O.
- OSTI ID:
- 135992
- Journal Information:
- High Energy Chemistry, Journal Name: High Energy Chemistry Journal Issue: 1 Vol. 29; ISSN 0018-1439; ISSN HIECAP
- Country of Publication:
- United States
- Language:
- English
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