Pulse radiolytic studies of electron transfer processes and applications to solar photochemistry

Technical Report · Fri Jan 17 04:00:00 EST 1992

OSTI ID:6287398

Neta, P

The studies use pulse radiolysis to provide absolute rate constants for reactions of many inorganic radicals and organic peroxyl radicals, key intermediates in many chemical processes, and to study electron transfer reactions of metalloporphyrins for solar energy conversion. Highlights of research during the past 3 years are: metalloporphyrins and colloidal catalysts, inorganic radicals, peroxyl radicals, and other topics.

• Research Organization: National Inst. of Standards and Technology, Gaithersburg, MD (United States). Chemical Kinetics and Thermodynamics Div.
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: AI05-83ER13108
• OSTI ID: 6287398
• Report Number(s): DOE/ER/13108-T7; ON: DE93018016
• Country of Publication: United States
• Language: English

Related Subjects

14 SOLAR ENERGY
140505* -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
ANIONS
ASCORBIC ACID
CARBOXYLIC ACIDS
CATIONS
CHARGED PARTICLES
CHEMICAL REACTIONS
CHROMIUM COMPLEXES
COBALT COMPLEXES
COMPLEXES
CONVERSION
DOCUMENT TYPES
ELECTRON TRANSFER
ENERGY CONVERSION
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
IONS
NICKEL COMPLEXES
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
OXIDATION
PEROXY RADICALS
PHOTOSENSITIVITY
PORPHYRINS
PROGRESS REPORT
RADICALS
REAGENTS
SENSITIVITY
SENSITIZERS
SOLAR ENERGY CONVERSION
SOLVENTS
TRANSITION ELEMENT COMPLEXES
VITAMINS