Pulse radiolytic studies of electron transfer processes and applications to solar photochemistry. Progress report, [February 1989--April 1990]

Technical Report · Fri Apr 20 04:00:00 EDT 1990

OSTI ID:10169531

Neta, P

Pulse radiolysis can provide absolute rate constants for reactions of many inorganic radicals and organic peroxyl radicals, key intermediates in many chemical processes. Emphasis of this work is electron transfer reactions of metalloporphyrins that may be applicable to solar energy conversion systems. Highlights of research during the past year are: metalloporphyrins and colloidal catalysts, peroxyl radicals, inorganic radicals, other topics.

• Research Organization: National Inst. of Standards and Technology, Gaithersburg, MD (United States). Chemical Kinetics Div.
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: AI05-83ER13108
• OSTI ID: 10169531
• Report Number(s): DOE/ER/13108--T6; ON: DE93018005
• Country of Publication: United States
• Language: English

Related Subjects

14 SOLAR ENERGY
140505
ASCORBIC ACID
CHEMICAL REACTIONS
COBALT COMPLEXES
ELECTRON TRANSFER
IRIDIUM COMPLEXES
NICKEL COMPLEXES
ORGANIC BROMINE COMPOUNDS
ORGANIC SOLVENTS
OXIDATION
PEROXY RADICALS
PHENOLS
PHOTOCHEMICAL, PHOTOBIOLOGICAL, AND THERMOCHEMICAL CONVERSION
PHOTOSENSITIVITY
PORPHYRINS
PROGRESS REPORT
RADIOLYSIS
SENSITIZERS
SOLAR ENERGY CONVERSION