Pulse radiolytic studies of electron transfer processes and applications to solar photochemistry

Technical Report · Fri Apr 20 04:00:00 EDT 1990

OSTI ID:6158267

Neta, P

Pulse radiolysis can provide absolute rate constants for reactions of many inorganic radicals and organic peroxyl radicals, key intermediates in many chemical processes. Emphasis of this work is electron transfer reactions of metalloporphyrins that may be applicable to solar energy conversion systems. Highlights of research during the past year are: metalloporphyrins and colloidal catalysts, peroxyl radicals, inorganic radicals, other topics.

• Research Organization: National Inst. of Standards and Technology, Gaithersburg, MD (United States). Chemical Kinetics Div.
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: AI05-83ER13108
• OSTI ID: 6158267
• Report Number(s): DOE/ER/13108-T6; ON: DE93018005
• Country of Publication: United States
• Language: English

Related Subjects

14 SOLAR ENERGY
140505* -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
AROMATICS
ASCORBIC ACID
CARBOXYLIC ACIDS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
COBALT COMPLEXES
COMPLEXES
CONVERSION
DECOMPOSITION
DOCUMENT TYPES
ELECTRON TRANSFER
ENERGY CONVERSION
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDROXY COMPOUNDS
IRIDIUM COMPLEXES
NICKEL COMPLEXES
ORGANIC ACIDS
ORGANIC BROMINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
OXIDATION
PEROXY RADICALS
PHENOLS
PHOTOSENSITIVITY
PORPHYRINS
PROGRESS REPORT
RADIATION EFFECTS
RADICALS
RADIOLYSIS
REAGENTS
SENSITIVITY
SENSITIZERS
SOLAR ENERGY CONVERSION
SOLVENTS
TRANSITION ELEMENT COMPLEXES
VITAMINS