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Formaldehyde in the synthesis of nitroxyl biradicals

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:6227495
Methylenebispiperidonoxyl biradicals are formed upon the condensation of 2,2,6,6-tetramethyl-4-oxopiperidin-1-oxyl with formaldehyde in mole ratio from 1:0.5 to 1:1.5 in aqueous alkaline medium. 3-Methylene-2,2,6,6-tetramethyl-4-oxopiperidin-1-oxyl radicals dimerize upon prolonged standing through a Diels-Alder reaction, while they undergo Michael self-condensation in dilute aqueous alkaline medium.
Research Organization:
Institute of Chemical Physics, Moscow, USSR
OSTI ID:
6227495
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:8; ISSN BACCA
Country of Publication:
United States
Language:
English