Hydrosilylation of unsaturated compounds in the presence of thiourea complexes of Pt(II) and Pd(II)

Journal Article · Tue May 10 00:00:00 EDT 1988 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6180770

Brovko, V S; Vorb'ev-Desyatovskii, N V; Kukushkin, Yu N

Transition metal complexes, in particular H/sub 2/(PtCl/sub 6/), are effective catalysts in hydrosilylation reactions: the reaction of silanes and their substituted derivatives with olefins and acetylenes. The authors have shown that thiourea complexes of Pt(II) of the cationic type may catalyze hydrosilylation of 1-hexene and phenylacetylene by methyldichlorosilane. Terminal addition products are formed, and the reaction is characterized by 100% selectivity.

• Research Organization: Lensovet Leningrad Technological Institute (USSR)
• OSTI ID: 6180770
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Appl. Chem. USSR (Engl. Transl.); (United States) Vol. 60:11; ISSN JAPUA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
AROMATICS
CARBONIC ACID DERIVATIVES
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPLEXES
HEPTENES
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC ION EXCHANGERS
ORGANIC POLYMERS
ORGANIC SILICON COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PALLADIUM COMPLEXES
PETROCHEMICALS
PETROLEUM PRODUCTS
PLATINUM COMPLEXES
POLYMERS
REACTION KINETICS
REDUCTION
RESINS
SEPARATION PROCESSES
SILANES
SILICON COMPOUNDS
THIOUREAS
TOLAN
TRANSITION ELEMENT COMPLEXES
YIELDS