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Hydrosilylation reactions of hydrosilatrane and 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
DOI:https://doi.org/10.1007/BF00954236· OSTI ID:6417041
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The authors have investigated the reaction of 1-hydrosilatrane (I) with a series of unsaturated compounds in benzene (1-hexene, 1-vinylsilatrane, 1-hexyne, phenylacetylene, propargyl chloride, and vinyl acetylene) using known methods for inducing hydrosilylation. The catalysts used included H/sub 2/PtCl/sub 6/, Et/sub 3/N, palladium and rhodium complexes and tert-butyl and benzoyl peroxides. Neither these nor thermal or photochemical initiation led to the expected result, and in no case did (I) take part in the reaction. 1-Hydrosilatrane does not react with monosubstituted ethylenes (or acetylenes) either in the presence of platinum or rhodium complexes or upon initiation of the reactions using organic peroxides, UV irradiation, or thermal methods. By contrast, 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane readily takes part in hydrosilylation of the indicated unsaturated compounds when Rhacac (CO)/sub 2/ is present.
Research Organization:
Institute of Organic Chemistry, Irkutsk, USSR
OSTI ID:
6417041
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:4; ISSN BACCA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETYLENE
ALKANES
ALKENES
ALKYNES
BINDING ENERGY
CARBON
CARBON 13
CARBON ISOTOPES
CARBONYLS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTION YIELD
COMPLEXES
COMPLEXOMETRY
CYCLOALKANES
ELECTRONS
ELEMENTARY PARTICLES
ELEMENTS
ENERGY
ETHYLENE
EVEN-ODD NUCLEI
FERMIONS
HYDRIDES
HYDROCARBONS
HYDROGEN
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
ISOTOPES
LEPTONS
LIGHT NUCLEI
NMR SPECTRA
NONMETALS
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC SILICON COMPOUNDS
PLATINUM COMPLEXES
RHODIUM COMPLEXES
SEMIMETALS
SILANES
SILICON
SILICON 29
SILICON COMPLEXES
SILICON COMPOUNDS
SILICON ISOTOPES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
YIELDS