Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Transformations of propene under the action of hydrogen chloride and oxygen at CuCl/sub 2/-Al/sub 2/O/sub 3/ catalyst (in Russian)

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6136501
;
By ESR in conjunction with the freezing out of the radicals during the oxidative chlorination of propene it was shown that allyl radicals are mostly formed as a result of the transfer of a chlorine atom from the copper(II) chloride, deposited on ..cap alpha..-aluminum oxide, to the substrate. The direct introduction of the catalyst into the resonance cavity with or without the delivery of hydrogen chloride and oxygen led to the superimposition of the spectra of C/sub 3/H/sub 5/ radicals and paramagnetic copper ions. The variation of the concentration of the allyl radicals as a function of temperature is extremal in nature. The kinetic parameters of the elementary reactions C/sub 3/H/sub 6/ + Cl ..cap alpha.. C/sub 3/H/sub 5/ + HCl and C/sub 3/H/sub 6/ + CuCl/sub 2/ ..-->.. C/sub 3/H/sub 5/ + HCl + CuCl were determined. The activation energies of these reactions amount to 4.2 and 2.5 kJ/mole respectively.
Research Organization:
Ufa Petroleum Institute, USSR
OSTI ID:
6136501
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 22:3; ISSN JOCYA
Country of Publication:
United States
Language:
Russian

Similar Records

Synthesis and ESR investigation of new stable phenoxyl radicals and their complexes with transition metals based on 3-(3,5-di-tert-butyl-4-hydroxyanilino)-1-phenyl-2-propen-1-one
Journal Article · Sun Aug 10 00:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States) · OSTI ID:5353373
Rate constants of the reactions of Re(CO)/sub 5/ radicals with organic halides determined using ESR spectroscopy
Journal Article · Sun Nov 09 23:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) · OSTI ID:6357639
Redox electromotive force measurements in the molten CuCl-CuCl/sub 2/ system and thermodynamic properties of liquid CuCl/sub 2/
Journal Article · Sat Dec 31 23:00:00 EST 1983 · J. Chem. Eng. Data; (United States) · OSTI ID:6553405

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKENES
ALKYL RADICALS
ALLYL RADICALS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISORPTION
CHLORIDES
CHLORINATION
CHLORINE COMPOUNDS
COPPER CHLORIDES
COPPER COMPOUNDS
COPPER HALIDES
ELECTRON SPIN RESONANCE
ENERGY
EPR SPECTROMETERS
HALIDES
HALOGEN COMPOUNDS
HALOGENATION
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
HYDROGEN TRANSFER
INORGANIC ACIDS
KINETICS
MAGNETIC RESONANCE
MAGNETISM
MEASURING INSTRUMENTS
ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PARAMAGNETISM
PROPYLENE
QUANTITY RATIO
RADICALS
REACTION KINETICS
REDUCTION
RESONANCE
SEPARATION PROCESSES
SORPTION
SPECTROMETERS
TEMPERATURE DEPENDENCE
TRANSITION ELEMENT COMPOUNDS