Redox electromotive force measurements in the molten CuCl-CuCl/sub 2/ system and thermodynamic properties of liquid CuCl/sub 2/
Journal Article
·
· J. Chem. Eng. Data; (United States)
Cu(I)/Cu(II) redox electromotive force measurements in the molten binary system CuCl-CuCl/sub 2/ were carried out by using a chlorine/chloride reference electrode in a temperature range from about 400 to 530/sup 0/C and for several concentrations up to 10 mol % CuCl/sub 2/. The free energy, enthalpy, and entropy change of the reaction CuCl(l) + 1/2Cl/sub 2/(g) = CuCl/sub 2/(l), as well as the unknown thermodynamic properties of molten solute CuCl/sub 2/, have been calculated as a function of temperature.
- Research Organization:
- Lehrstuhl fur Technische Thermodynamik an der RWTH Aachen
- OSTI ID:
- 6553405
- Journal Information:
- J. Chem. Eng. Data; (United States), Journal Name: J. Chem. Eng. Data; (United States) Vol. 29:1; ISSN JCEAA
- Country of Publication:
- United States
- Language:
- English
Similar Records
A THERMODYNAMIC STUDY OF THE REACTION UO$sub 2$(s) + 1/2 C(gr) + Cl$sub 2$(g) = UOCl$sub 3$(s) + 1/2CO$sub 2$(g) BY THE ELECTROMOTIVE FORCE METHOD
Determination of thermodynamics and kinetics of point defects in Cu{sub 2}O using the Rosenburg method
Thermodynamic properties of iron and nickel chloride solutions in molten LiCl-KCl
Journal Article
·
Wed Jan 20 23:00:00 EST 1960
· Doklady Akad. Nauk S.S.S.R.
·
OSTI ID:4198299
Determination of thermodynamics and kinetics of point defects in Cu{sub 2}O using the Rosenburg method
Journal Article
·
Sun Feb 28 23:00:00 EST 1999
· Journal of the Electrochemical Society
·
OSTI ID:345387
Thermodynamic properties of iron and nickel chloride solutions in molten LiCl-KCl
Journal Article
·
Wed Jan 23 23:00:00 EST 1991
· Journal of Physical Chemistry; (USA)
·
OSTI ID:5940786
Related Subjects
36 MATERIALS SCIENCE
360104* -- Metals & Alloys-- Physical Properties
BINARY MIXTURES
CALCULATION METHODS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE
CHLORINE COMPOUNDS
COPPER CHLORIDES
COPPER COMPOUNDS
COPPER HALIDES
DISPERSIONS
ELECTROMOTIVE FORCE
ELEMENTS
FLUIDS
HALIDES
HALOGEN COMPOUNDS
HALOGENS
HIGH TEMPERATURE
KINETICS
LIQUID METALS
LIQUIDS
MEASURING METHODS
METALS
MIXTURES
NONMETALS
PHYSICAL PROPERTIES
QUANTITY RATIO
REACTION KINETICS
REDOX POTENTIAL
REDUCTION
TEMPERATURE DEPENDENCE
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS
360104* -- Metals & Alloys-- Physical Properties
BINARY MIXTURES
CALCULATION METHODS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE
CHLORINE COMPOUNDS
COPPER CHLORIDES
COPPER COMPOUNDS
COPPER HALIDES
DISPERSIONS
ELECTROMOTIVE FORCE
ELEMENTS
FLUIDS
HALIDES
HALOGEN COMPOUNDS
HALOGENS
HIGH TEMPERATURE
KINETICS
LIQUID METALS
LIQUIDS
MEASURING METHODS
METALS
MIXTURES
NONMETALS
PHYSICAL PROPERTIES
QUANTITY RATIO
REACTION KINETICS
REDOX POTENTIAL
REDUCTION
TEMPERATURE DEPENDENCE
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS