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Kinetics and mechanism of the liquid-phase oxidation of cyclohexene. V. Oxidation of cyclohexene in the presence of bimetallic catalysts

Journal Article · · Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6093727
; ;
The kinetics of the liquid-phase oxidation of cyclohexene in the presence of homogeneous bimetallic catalysts Co-V, Pb-V, Pb-Mo was investigated. It was shown that the activity of the bimetallic catalyst found is determined to a large degree by the nature of the epoxiding metal. A general model is proposed for the oxidation of cyclohexene in the presence of bimetallic catalysts.
Research Organization:
D.I. Mendeleev Chemico-technological Institute, Moscow (USSR)
OSTI ID:
6093727
Journal Information:
Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 29:3; ISSN KICAA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
BIMETALS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
COBALT COMPOUNDS
CYCLOALKENES
DECOMPOSITION
EPOXIDES
HETEROGENEOUS CATALYSIS
HYDROCARBONS
KINETICS
MATHEMATICAL MODELS
MOLYBDENUM COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PEROXIDES
REACTION KINETICS
REDOX POTENTIAL
REFRACTORY METAL COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
YIELDS