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Kinetics and mechanism of the liquid-phase oxidation of cyclohexene. IV. Decomposition of cyclohexenyl hydroperoxide in the presence of bimetallic catalysts

Journal Article · · Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6089792
; ;

The kinetic principles of the decomposition of cyclohexenyl hydroperoxide in cyclohexene solution in homogeneous catalysis by vanadium-containing bimetallic systems were investigated. For Co-V and Pb-V, the formation of complexes with low activity in catalysis was demonstrated by kinetic and spectral methods. A mathematical model was obtained for the process, adequately describing the conversions of cyclohexenyl hydroperoxide in the presence of bimetallic systems.

Research Organization:
D.I. Mendeleev Chemico-technological Institute, Moscow (USSR)
OSTI ID:
6089792
Journal Information:
Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 29:3; ISSN KICAA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
BIMETALS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COBALT COMPLEXES
COBALT COMPOUNDS
COMPLEXES
COMPLEXOMETRY
CYCLOALKENES
DECOMPOSITION
HYDROCARBONS
KINETICS
LEAD COMPLEXES
LEAD COMPOUNDS
MATHEMATICAL MODELS
ORGANIC COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PEROXIDES
REACTION KINETICS
SPECTRA
SPECTRAL SHIFT
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
ULTRAVIOLET SPECTRA
VANADIUM COMPLEXES
VANADIUM COMPOUNDS